Ushbu maqolada reniy metallini ajratib olish, qayta ishlash boyitish usullari haqida umumiy ma’lumot berilib, bugungi kunda reniyning asosiy qo‘llanilishi aviatsiyada gaz turbinalari uchun super qotishmalarda bo‘lib, neftni qayta ishlash katalizatorlarida foydalanish umumiy iste’molning taxminan 10% ni tashkil qiladi. Reniy -1 dan +7 gacha bo‘lgan bir nechta oksidlanish darajasiga ega, eng keng tarqalganlari +7, +6, +5 va +4. U bir oksidlanish holatidan ikkinchisiga osonlik bilan o‘zgaradi, bu jarayon reniy metallini katalizator sifatida ishlatish uchun eng muhim metal hisoblanadi. Ba’zi sulfat kislota va boshqa aralashmalarni o‘z ichiga olgan eritma, erituvchi ekstraktsiyasi yoki qattiq qatlamli ion almashinuvi orqali reniyni qayta tiklashga tayyorlash uchun qayta ishlash haqida ma’lumot berilgan.
В данной статье представлен обзор методов извлечения и переработки металлического рения. Сегодня основное применение рения приходится на суперсплавы для газовых турбин в авиации, а его использование в катализаторах нефтепереработки составляет около 10% от общего потребления. Рений имеет несколько степеней окисления от -1 до +7, наиболее распространенными являются +7, +6, +5 и +4. Он может легко переходить из одной степени окисления в другую, и этот процесс делает металлический рений наиболее важным металлом для использования в качестве катализатора. Сообщается, что раствор, содержащий некоторое количество серной кислоты и других примесей, обрабатывается для подготовки рения для извлечения путем экстракции растворителем или ионного обмена в твердом слое.
Ushbu maqolada reniy metallini ajratib olish, qayta ishlash boyitish usullari haqida umumiy ma’lumot berilib, bugungi kunda reniyning asosiy qo‘llanilishi aviatsiyada gaz turbinalari uchun super qotishmalarda bo‘lib, neftni qayta ishlash katalizatorlarida foydalanish umumiy iste’molning taxminan 10% ni tashkil qiladi. Reniy -1 dan +7 gacha bo‘lgan bir nechta oksidlanish darajasiga ega, eng keng tarqalganlari +7, +6, +5 va +4. U bir oksidlanish holatidan ikkinchisiga osonlik bilan o‘zgaradi, bu jarayon reniy metallini katalizator sifatida ishlatish uchun eng muhim metal hisoblanadi. Ba’zi sulfat kislota va boshqa aralashmalarni o‘z ichiga olgan eritma, erituvchi ekstraktsiyasi yoki qattiq qatlamli ion almashinuvi orqali reniyni qayta tiklashga tayyorlash uchun qayta ishlash haqida ma’lumot berilgan.
This article provides an overview of rhenium metal extraction and processing methods. Today, the main use of rhenium is in superalloys for gas turbines in aviation, and its use in petroleum refining catalysts accounts for about 10% of total consumption. . Rhenium has several oxidation states from -1 to +7, the most common being +7, +6, +5, and +4. It can easily change from one oxidation state to another, a process that makes rhenium metal the most important metal to use as a catalyst. A solution containing some sulfuric acid and other impurities is reported to be processed to prepare rhenium for recovery by solvent extraction or solid-bed ion exchange.
| № | Муаллифнинг исми | Лавозими | Ташкилот номи |
|---|---|---|---|
| 1 | Xakimov K.J. | доктор технических наук, доцент | Термизского инженерно-технологического института |
| 2 | Rajabov S.X. | ассистент | Термизского инженерно-технологического института |
| № | Ҳавола номи |
|---|---|
| 1 | Bernard, A Volatile transport and deposition of Mo, W and Re in high temperature magmatic fluids / Bernard A., Symonds R.B., Rose W.I. // Applied Geochemistry 5 – 1990 – P. 317–326. |
| 2 | Bernard, A. Dumortier, P. Identification of natural rhenium sulfide (ReS2) in volcanic fumaroles from the Usu volcano, Hokkaido, Japan. Proceedings of the XIth International Congress on Electron Microscopy (Kyoto) / A. Bernard, P. Dumortier //– 1986 – P. 1691–1692. |
| 3 | Besser, A.D. The perspectives of the development of the rhenium’s production in Russia. In: Bryskin, D.D. (ed.) Rhenium and Rhenium Alloys. / Besser A.D., Peredereev A.V., Tarasov A.V. // The Minerals, Metals and Materials Society, Warrendale, PA, USA – 1997 – P. 59–65. |
| 4 | Chekmarev, A.M. Associated rhenium extraction in complex processing of productive solutions of underground uranium leaching / A.M. Chekmarev, I.D. Troshkina, Y.V. Nesterov, A.B. Maiboroda, O.N. Ushanova, N.S. Smirnov // Chemistry for Sustainable Development 12 – 2004 – P. 113–117. |
| 5 | Copper Statistics and Information [Электронный ресурс]. – Режим доступа: https://www.usgs.gov/centers/nmic/copper-statistics-and-information, свободный |
| 6 | Dare, S.A.S. Chalcophile and platinum-group element (PGE) concentrations in the sulfide minerals from the McCreedy East deposit, Sudbury, Canada, and the origin of PGE in pyrite. / Dare, S.A.S., Barnes S.J., Prichard H.M., Fisher P.C. // Mineralium Deposita 46 – 2011 – P. 381–407. |
| 7 | Dare, S.A.S. The timing and formation of platinumgroup minerals from the Creighton Ni-Cu-platinumgroup element sulfide deposit, Sudbury, Canada: early crystallization of PGE-rich sulfarsenides. / Dare S.A.S., Barnes S.J., Prichard H.M., Fisher P.C., // Economic Geology 105 – 2010 – P. 1071–1096. |
| 8 | Fraser, R.D., Giroux, G.H., Form 43–101 Technical Report on the Anna Lake Uranium Project, Central Mineral Belt, Labrador, Canada; Prepared for Bayswater Uranium Corp. – 2009 - pp. 94. |
| 9 | Genkin, A.D. New data on dzhezkazganite – rhenium-molybdenum- copper-lead sulfide – from the Dzhezkazgan deposit (Kazakhstan). / Genkin A.D., Poplavko E.M., Gorshkov A.I., Tsepin A.I. , Sivtsov A.V. // Geology of Ore Deposits 36 – 1994 – P. 481–489. |
| 10 | Habashi, F., Rhenium Seventy Years Old, In: Bryskin, B.D (ed.) Rhenium and Rhenium Alloys// TMS, Warrendale, PA, USA. – 1996. |
| 11 | Hitzman, M. The sediment-hosted stratiform copper ore system / Hitzman M., Kirkham R., Broughton D., Thorson J., Selley D. // Economic Geology 100th Anniversary Volume – 2005 – P. 609–642. |
| 12 | Hu, H. High sensitivity thiocyanate spectrophotometric method for determination of perrhenate, an analogue of radioactive pertechnetate, under acidic condition / H. Hu, L.L. Sun, Y.L. Gao, T. Wang, Y.F. Zhang, H.X. Wu, X.H. Chen. // Chemical Papers May 2019, Volume 73, Issue 5, pp 1093–1101. |
| 13 | Ignatovich, A. Extraction of copper and silver from ammoniacal leaching solutions of copper smelting slag / A.S. Ignatovich // Scientific Reports on Resource Issues. – Freiberg, Germany: IUR Office, 2018. – Volume 1. – P.203-209. |
| 14 | Ignatovich, A.S. Extraction of rhenium from ammoniacal leaching solutions of copper smelting slag and model solutions / A.S. Ignatovich, D.S. Lutskiy, R.R. Khismatullin // Journal of mining and geological sciences. – 2019 – 62(2) – P.129-131. |
| 15 | Knutton, S. Copper the enduring metall / S. Knutton // Education in Chemistry. – 1986. – Vol. 23. – № 5. – P. 135-137. |