322

  • Web Address
  • DOI
  • Date of creation in the UzSCI system 23-07-2021
  • Read count 322
  • Date of publication 27-03-2021
  • Main LanguageIngliz
  • Pages277-284
Tags
Ўзбек

In this article, kinetic feature of N, N-diallylpiperidine bromide radical polymerization is investigated. Orders of reaction are determined by the monomer and by the initiator. Essential value in this regard acquire investigation of implementation mechanism on elementary acts of radical polymerization N-alkyl - N, N-diallylamines and their proton salts at initial extents of transformation in water and water-organic solutions.

Specific cyclolinear polymerization of diallyl monomers salt allows excluding the act degraded transfer of the chain on monomer and gives the chance of receiving polymers with high molecular weight. Data of kinetic researches testify the lack of degradation inherent chain transfer. It is noted that polymerization rate decreases while adding monomer ethanol to water solution.

NMR 13C-spectroscopic researches of the polymers received by radical polymerization of N, N-diallylpiperidine bromide testifies the existence in chains of macromolecules as to five - (48%), and six-membered cycles (52%) which are calculated from a ratio of intensity of signals of the corresponding carbon atoms.

The combination of polymeric, surface active and electrolytic properties of the synthesized polymer leads to the new qualitative state possessing a number of specific features shown in conformational and electrochemical behavior of polymer solution. Finding these properties will cause assessment opportunities of synthesized polymer usage as cationic flocculants, coagulants, precipitators and other purposes.

Therefore, as distinct from anion and nonionic flocculants, cationic flocculants show high efficiency on application of them for extraction of organic and colloidal pollution and sedimentation of the weighed particles. Besides big advantage of cationic flocculants is the absence of their corrosion action on metals.

№ Author name position Name of organisation
1 Ayubova I.X. Dotsent TDTU
2 Safayev U.A. Professor TDTU
3 Khodjayev S.F. O'qituvchi TDTU
4 Ziyayeva M.A. Katta o'qituvchi TDTU
5 Tashkarayev R.A. Professor University of friendship of peoples academician A. Kuatbekov
№ Name of reference
1 1. Kuzmina E.A., Kondrateva O.S., Kleshseva N.A., Timofeeva L.M., Shtilman M.I. 2003. Properties of new synthesized polymers on the basis of diallylmethylamine. Russia// Journal: Achievements in chemistry and chemical technology. T.17. V.5: P. 86-90.
2 2. Almova A.A. 2011. Synthesis and research of physical and chemical properties of Poly-N, acid N-diallylamineethanol. //Journal: World Discoveries. T.9.1. V.21: P. 355-362.
3 3. Topchiyev D.A., Nazhmetdinova G.T., Krapivin A.M., and Shreyder V. A. 1982. About cycloline polymers structure of N, N- dialkyl-N, N-diallilammoniumgalogenides //Journal: High molecular compounds. T.24. V.6: P. 473.
4 4. Gordon A. 1976. Companion of the chemist. P.539.
5 5. Topchiyev D.A., Malkanduyev Yu.A. Cationic polyelectrolytes: receiving, properties and application. M.: IKTs "Akademkniga", 2004. -232 p.
6 6. Safayev U.A., Musayev M.N., Xodjayev Sh.F. Osobennosti radikal’noy polimerizatsii diallilovogo monomera na osnove bromistogo allila i piperidina. Tashkent, Vestnik TashGTU, 2015. - №1. - S.143-149.
7 7. Riskiyev F.F., Xodjayev Sh.F. Osobennosti radikal’noy polimerizatsii diallilovogo monomera na osnove allilbromida i piperidina. Sbornik dokladov respublikanskoy nauchnoy konferensii «Rol’ intellektual’noy molodeji v razvitii nauki i texniki». Tashkent, TashGTU, 2015. - CH. 1. - S.267-269.
8 8. Safayev U.A., Ibragimov A.A., Valiyev M.A. Ispol’zovaniye polielektrolitov s geterotsiklicheskimi gruppami dlya ochistki stochnix vod // Trudi nauchno-prakticheskoy konferensii “Rol’ i mesto ekologicheskogo obrazovaniya v XXI veke: resheniya ekologicheskix problem texnogennix proizvodstv” 25 noyabrya 2015 g. –S.222-224.
9 9. Timofeyeva L.M., Klesheva H.A., Vasil’yeva YU.A., Gromova G.L., Timofeyeva G.I., Filatova M.P. Mexanizm i kineticheskiye osobennosti protsessov polucheniya novix polimerov na osnove monomerov ryada diallilamina. // Visokomolek. soyedin. 2005. - T. 203. - №6. - S.916-933.
10 10. Clayden J., Greeves N., Warren S. Organic Chemistry. 2nd Edition. Oxford University Press, 2012. - 1234 р.
11 11. Morrison R.T., Boyd R.N. Organic chemistry. 7th Edition. Pearson, India, 2011. - 1508 p.
12 12. Safaev U.A., Khodjaev Sh.F., Safaev F.U., Ziyaeva M.A. Study of polymerizing the monomer of quaternary salts based on N, N - dimethylaminoethylmethacrylate and chloroacetate//Theoretical and Applied Sciences in the USA, proceedings of the 5th International scientific conference, New York, USA. August 26, 2015. - Р.30-34.
13 13. Kesavarao S., Shailaja D. Novel multifunctional hybrid diallyl ether monomer via azide alkyne click reaction as crosslinking agent in protective coatings. Polymer, Volume 62, 7 April 2015, P. 60-69.
14 14. Fu Liu, Bi-rong Ma, Dong Zhou, Li-Jing Zhu, Yin-Yi Fu, Li-xin Xue. Positively charged loose nanofiltration membrane grafted by diallyl dimethyl ammonium chloride (DADMAC) via UV for salt and dye removal. Reactive and Functional Polymers, Volume 86, January 2015, P. 191-198.
15 15. Tsvetkov N.V., Lezov A.A., Vlasov P.S., Lezova A.A., Samokhvalova S.A., Lebedeva E.V., Polushina G.E. Copolymers of diallyldimethylammonium chloride and 2-(diallyl(methyl) ammonio) acetate: Effect of composition and ionic strength on conformational properties. European Polymer Journal, Volume 84, November 2016, P. 268-278.
16 16. Ali M.M., Perzanowski H.P., Ali Sk.A. Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte–electrolyte). Polymer, Volume 41, Issue 15, July 2000, P. 5591-5600.
Waiting