193

A new pilot-plant equipment of an inclined rotary furnace for the processing of fluoroammonium silicon-containing materials has been developed and manufactured, which allowed sublimation of ammonium hexafluorosilicate, formed as a result of fluorination of processed raw materials, in two sections, with autonomous control of temperature and movement of raw materials. It is shown that the use of the created equipment for the processing of copper-smelting slags of the Almalyk MMC using fluoride technology makes it possible to separate amorphous silicon dioxide in the form of a dispersed powder from slags, extract iron and obtain a collective concentrate of precious, non-ferrous and other metals. It is shown that the maximum temperature during the processing of copper slags according to the proposed technology is no more than 400°C, and the chemical reagent used is regenerated and returned to the beginning of the technological process. The main parameters and the operation principle of the new device, and as well particle size distribution and textural characteristics of amorphous silicon dioxide synthesized by this equipment are presented.

  • Web Address
  • DOI
  • Date of creation in the UzSCI system04-11-2022
  • Read count193
  • Date of publication30-09-2022
  • Main LanguageIngliz
  • Pages37-45
English

A new pilot-plant equipment of an inclined rotary furnace for the processing of fluoroammonium silicon-containing materials has been developed and manufactured, which allowed sublimation of ammonium hexafluorosilicate, formed as a result of fluorination of processed raw materials, in two sections, with autonomous control of temperature and movement of raw materials. It is shown that the use of the created equipment for the processing of copper-smelting slags of the Almalyk MMC using fluoride technology makes it possible to separate amorphous silicon dioxide in the form of a dispersed powder from slags, extract iron and obtain a collective concentrate of precious, non-ferrous and other metals. It is shown that the maximum temperature during the processing of copper slags according to the proposed technology is no more than 400°C, and the chemical reagent used is regenerated and returned to the beginning of the technological process. The main parameters and the operation principle of the new device, and as well particle size distribution and textural characteristics of amorphous silicon dioxide synthesized by this equipment are presented.

Name of reference
1 K.S. Sanakulov. “Scientific and technical bases for the processing of waste from mining and metallurgical production”, 2009. 439.
2 K.S. Sanakulov., A.S. Khasanov. “Processing of slag from copper production”, 2007. 256
3 A.A. Yusupkhodjaev., Sh.T. Khojiev., B.T. Berdiyarov., D.O. Yavkochiva., J.B. Ismailov. Technology of processing slags of copper production using local secondary technogenic formations. “International journal of innovative technology and exploring engineering”, 2019. 5461.
4 K.Zh. Khakimov., A.S. Khasanov., O.A. Kayumov., A.Y. Shukurov. Study of the chemical material composition of slags of copper-melting production, cliners and other waste of metallurgical production. “Universum: electronic scientific journal”, 2021. 83
5 L.P Demyanova., A.S. Buinovsky., V.S. Rimkevich., Y.N. Malovitsky. Rational processing of quartz-containing raw materials by fluoride method. “Bulletin of the Tomsk Polytechnic University”, 2010. 77.
6 M.A. Medkov., G.F. Krysenko., D.G. Epov. “Method for opening fluorite”, 2011. 60.
7 S.Z. Isyangulov., S.V. Saveliev., A.A. Pupyshev., E.I. Melnichenko., D.G. Epov. Device for processing fluoroammonium silicon-containing products. “Patent RU 2233694”, 2003
8 A.N. Dyachenko., R.I. Kraydenko. “Proceedings of the 51Annual Conference of Metallurgists of CIM (COM 2012)”, 2012. 238
9 A.A. Chuiko. Medical chemistry and clinical use of silicon dioxide. “Scientific thought”, 2003. 414.
10 A. Tadayon., R. Jamshidi., A. Esmaeili. Delivery of tissue plasminogen activator and streptokinase magnetic nanoparticles to target vascular diseases. “International journal of pharmaceutics”, 2015. 428.
11 A.A. Chuiko., V.K. Burnt. Medical chemistri of nano disperse silica. “Chemistry, physics and surface technology”, 2006. 346
12 P.V. Grishin. “Bulletin of Kazan Technological University”, 2014. 239.
13 N.C. Camacho., J.R. Vega Baudrit., Y.C. Urena. “Organic Medicinal Chemistry. International”, 2018
14 N.V. Zajceva., M.A. Zemljanova., V.N. Zvezdin., A.A. Dovbysh., I.V. Gmoshinskij., S.A. Hotimchenko., I.V. Safenkova., T.I. Akaf'eva. Impact of silica diochide nanoparticles on the morphology of internal organs in rat’s bi oral supplementation. “Questions pitanija”, 2016. 80
15 R. Yusoff., L.T.H. Nguyen., P. Chiew., Z.M. Wang., K.W. Nguyen. Comparative differences in the behavior of TiO2 and SiO2 food additives in food ingredient solutions. “Journal of nanoparticle research”, 2018. 76.
16 S. Das., J. Manam., S. K. Sharma. Role of rhodamine-B dye encapsulated mesoporous SiO2 in color tuning of SrAl2O4: Eu2 +, Dy3 + composite long lasting phosphorus. “Journal of materials science: materials in electronics”, 2016. 13217.
17 B.M. Abdurakhmanov., M.Sh. Kurbanov., S.A. Tulaganov., M. Ernazarov., L.S. Andriyko., A.I. Marinin., A.Y. Shevchenko. Synthesis of highly dispersed powders of amorphous silicon dioxide from man-made metallurgical wastes. “Uzbek Physics Journal”, 2021. 65.
18 M. Medkov., G. Krysenko., D. Epov., P. Sitnik., V. Avramenko. VII International scientific conference problems of complex development of georesources. “E3S Web of Conferences”, 2018. 56
19 A.W. Adamson., A.P. Gast. “Physical chemistry of surface/ 6th edition, Wiley”, 1997
20 V.S. Rimkevich., A.A. Pushkin., I.V. Girenko. Prospects of complex processing of the highsiliceous technogenic waste of thermal power plants. “Proceedings of the Samara scientific center of the Russian Academy of Sciences”, 2015. 304
21 S.J. Gregg., K.S.W. Sing. Adsorption, surface area and porosity. “Academic press”, 1982.
22 A.N. Dyachenko., R.I. Kraidenko. Separation of silicon-iron-copper-nickel concentrate by ammonium fluoride method into individual oxides. “Bulletin of the Tomsk Polytechnic University”, 2007. 38
23 M.Sh. Kurbanov., S.A. Tulaganov., M. Ernazarov., L.S. Andriyko., A.I. Marinin., A.Y. Shevchenko. Properties of amorphous silica synthesized from copper-smelting slags. “Journal of nano- and electronic physics”, 2021. 6.
24 V.M. Gunko. “Applied surface science”, 2014. 444.
Waiting