The purpose of this work is the chemical modification of cotton fabrics with natural
globular protein. Modification was carried out in the process of finishing cotton fabrics, after
decoction and bleaching in a continuous mode. The effect of modification on the strength, protein
content and functional groups of cotton fabric has been studied. According to the results obtained
using the AUTOGRAPH AGS-N machine, it was found that the modification of cotton fabrics with a
solution of globular protein increases the strength of the treated fabrics, depending on the
concentration of the modifier and the temperature regime. Treatment with a highly concentrated
protein solution completely fills the fabric structure, which reduces strength and breathability. Due
to the fixation of the structure, the elongation at break is reduced to 15.5%, shrinkage - up to 1.6
times. High-temperature treatment of the fabric with a low concentration solution increases strength
and reduces shrinkage by 2 times. Apparently, the relatively high-temperature regime of impregnation
promotes better dissolution of the protein and thereby increases the diffusion of the protein into the
tissue structure. This is confirmed by the protein content in the modified sample determined on the
Hanon K1100F automatic analyzer. According to the results of IR Fourier spectral analysis, it was
found that the modification of cotton fabrics with globule protein leads to an increase in hydrogen
bonds of various nature, a decrease in the number of characteristic -CH2- and -CH3 groups of the
protein globule in the spectrum. This may be due to the addition of protein to cellulose. Due to the
increase in functional groups in the structure of modified cellulose, hydrogen bonds increase, and a
decrease in the –COO– ion can be the reason for the chemical interaction of the ion with the hydroxyl
groups of cellulose.
The purpose of this work is the chemical modification of cotton fabrics with natural
globular protein. Modification was carried out in the process of finishing cotton fabrics, after
decoction and bleaching in a continuous mode. The effect of modification on the strength, protein
content and functional groups of cotton fabric has been studied. According to the results obtained
using the AUTOGRAPH AGS-N machine, it was found that the modification of cotton fabrics with a
solution of globular protein increases the strength of the treated fabrics, depending on the
concentration of the modifier and the temperature regime. Treatment with a highly concentrated
protein solution completely fills the fabric structure, which reduces strength and breathability. Due
to the fixation of the structure, the elongation at break is reduced to 15.5%, shrinkage - up to 1.6
times. High-temperature treatment of the fabric with a low concentration solution increases strength
and reduces shrinkage by 2 times. Apparently, the relatively high-temperature regime of impregnation
promotes better dissolution of the protein and thereby increases the diffusion of the protein into the
tissue structure. This is confirmed by the protein content in the modified sample determined on the
Hanon K1100F automatic analyzer. According to the results of IR Fourier spectral analysis, it was
found that the modification of cotton fabrics with globule protein leads to an increase in hydrogen
bonds of various nature, a decrease in the number of characteristic -CH2- and -CH3 groups of the
protein globule in the spectrum. This may be due to the addition of protein to cellulose. Due to the
increase in functional groups in the structure of modified cellulose, hydrogen bonds increase, and a
decrease in the –COO– ion can be the reason for the chemical interaction of the ion with the hydroxyl
groups of cellulose.
| № | Author name | position | Name of organisation |
|---|---|---|---|
| 1 | Saydalieva N.Z. | PhD | Tashkent Institute of Textile and Light Industry, Tashkent city, Republic of Uzbekistan |
| № | Name of reference |
|---|---|
| 1 | 1. Krichevskiy G.E. Khimicheskaya tekhnologiya tekstil'nykh materialov [Chemical technology of textile materials]. Moscow, 2000. Vol.1. p.173 – 177. 2. Qingbo Xu, Xinyu Wang, Peng Wang, Yanyan Zhang, Zongqian Wang. Durable antibacterial cotton fabric fabricated using a “self-created” mist polymerization device. International Journal of Biological Macromolecules, Volume 216, 2022, p.148-156, doi:10.1016/j.ijbiomac. 3. Jun li, Lihui Xu, Xiaoling Yuan, Hong Pan, Liming Wang, Yong Shen, Keting Li. Preparation of robust and self-healing superamphiphobic cotton fabrics based on modified silica aerogel particles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 651, 2022, , doi:10.1016/129634. 4. Dan-Dan Hu, Yi-Dong Li, Yunxuan Weng, HuaQiao Peng, Jian-Bing Zeng. Fabrication of sustainable and durable superwetting cotton fabrics with plant polyphenol for on-demand oil/water separation. Industrial Crops and Products,Volume 186, 2022, doi:10.1016/115264. |
| 2 | 5. Tianjie Niu, Yanxiu Wu, Xiaolei Zhai, Deshuai Sun, Long Fang, Xiaodong Zhang. Investigation on multifunctional modification of cotton fabrics for salt-free dyeing, resisting crease and inhibiting bacteria. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 648, 2022, doi:10.1016/129131. 6. Hongchen Liu, Yunlei Yin, Jinli Zhou, Hongying Yang, Lei Guo, Fang Peng, Haisong Qi. Fabrication of durable fluorescent and hydrophobic cotton fabrics by multiple surface modifications. Industrial Crops and Products, Volume 175, 2022, , doi: 10.1016/114238. 7. Yunlan Liu, Dan Ding, Yanfeng Lu, Yu Chen, Ying Liao, Guangxian Zhang, Fengxiu Zhang. Efficient and durable cotton fabric surface modification via flame retardant treatment. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 648, 2022, doi: 10.1016/129005. 8. Ying Liao, Yu Chen, Fengxiu Zhang. A biological reactive flame retardant for flame retardant modification of cotton fabric. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 630, 2021, , doi: 10.1016/127601. 9. M.Hedayet Ullah, Hasina Akther, M.Mahbubur Rahman, A.B.M. Foisal, M.Mahmud Hasan, S.M. Amir-Al Zumahi, Amun Amri. Surface modification and improvements of wicking properties and dyeability of grey jute-cotton blended fabrics using low-pressure glow discharge air plasma. Heliyon, Volume 7, Issue 8, 2021, e07893, ISSN 2405-8440, doi: 10.1016/ e07893. 10. Sidra, Shazia Tabasum, Khalid Mahmood Zia, Bushra Parveen, Muhammad Tahir Hussain. A novel water borne green textile polyurethane dispersions finishes from cotton (Gossypium arboreum) seed oil based polyol used in modification of cellulosic fabrics. Carbohydrate Polymer Technologies and Applications, Volume 2, 2021, 100170, ISSN 2666-8939, doi:.10.1016/100170. 11. Saydalieva N.Z., Khudayberdieva D.B., Suyunov J.B., Sultonoyozov X.B. Studying the nature influence film-forming on the quality of final finish of the cotton fabric. International Journal of Advanced Research in Science, Engineering and Technology. vol.6, Issue 10, October 2019. p: 11457-11460. 12. Saydalieva N., D. Khudayberdieva, Q. E. Sobirov. Modifikatsiya khlopchatobumazhnoj tkani v protsesse zaklyuchitel'noj otdelki. Tendentsii razvitiya legkoj promyshlennosti Respubliki Uzbekistan. Problemy, analiz i resheniya. Sbornik materialov mezhdunarodnoj onlajn konferentsii. 7.06.2020 g.TTYESI, doi.10.47100/conference_textile/S4_43 13. Yunhui Xu, Dingding Chen, Zhaofang Du, Jifeng Li, Yunxia Wang, Zhen Yang, Fengxia Peng. Structure and properties of silk fibroin grafted carboxylic cotton fabric via amide covalent modification. Carbohydrate Polymers, Volume 161, 2017, p. 99-108, doi. /10.1016/j.carbpol. 14. Saydalieva N.Z., Khudayberdieva D.B., F. Isamukhamedova, I. Shin. Integrated researches of the physical and mechanical properties of cotton fabric during its final finishing. E3S Web of Conferences 304, 03024 (2021) doi: 10.1051/ 03024. 15. Xu Yunhui, Huang Chen, Wang Xiaoming. Characterization and controlled release aloe extract of collagen protein modified cotton fiber. J: Carbohydr. Polym. 2013. 92, № 2, p. 982-988. 16. Hai Yan Zhang Study on Preparation of Modified Cotton with Collagen. J: Applied Mechanics and Materials. September. 2014. |
| 3 | 6. Hongchen Liu, Yunlei Yin, Jinli Zhou, Hongying Yang, Lei Guo, Fang Peng, Haisong Qi. Fabrication of durable fluorescent and hydrophobic cotton fabrics by multiple surface modifications. Industrial Crops and Products, Volume 175, 2022, , doi: 10.1016/114238. 7. Yunlan Liu, Dan Ding, Yanfeng Lu, Yu Chen, Ying Liao, Guangxian Zhang, Fengxiu Zhang. Efficient and durable cotton fabric surface modification via flame retardant treatment. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 648, 2022, doi: 10.1016/129005. 8. Ying Liao, Yu Chen, Fengxiu Zhang. A biological reactive flame retardant for flame retardant modification of cotton fabric. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 630, 2021, , doi: 10.1016/127601. 9. M.Hedayet Ullah, Hasina Akther, M.Mahbubur Rahman, A.B.M. Foisal, M.Mahmud Hasan, S.M. Amir-Al Zumahi, Amun Amri. Surface modification and improvements of wicking properties and dyeability of grey jute-cotton blended fabrics using low-pressure glow discharge air plasma. Heliyon, Volume 7, Issue 8, 2021, e07893, ISSN 2405-8440, doi: 10.1016/ e07893. |
| 4 | 10. Sidra, Shazia Tabasum, Khalid Mahmood Zia, Bushra Parveen, Muhammad Tahir Hussain. A novel water borne green textile polyurethane dispersions finishes from cotton (Gossypium arboreum) seed oil based polyol used in modification of cellulosic fabrics. Carbohydrate Polymer Technologies and Applications, Volume 2, 2021, 100170, ISSN 2666-8939, doi:.10.1016/100170. 11. Saydalieva N.Z., Khudayberdieva D.B., Suyunov J.B., Sultonoyozov X.B. Studying the nature influence film-forming on the quality of final finish of the cotton fabric. International Journal of Advanced Research in Science, Engineering and Technology. vol.6, Issue 10, October 2019. p: 11457-11460. 12. Saydalieva N., D. Khudayberdieva, Q. E. Sobirov. Modifikatsiya khlopchatobumazhnoj tkani v protsesse zaklyuchitel'noj otdelki. Tendentsii razvitiya legkoj promyshlennosti Respubliki Uzbekistan. Problemy, analiz i resheniya. Sbornik materialov mezhdunarodnoj onlajn konferentsii. 7.06.2020 g.TTYESI, doi.10.47100/conference_textile/S4_43 |
| 5 | 3. Yunhui Xu, Dingding Chen, Zhaofang Du, Jifeng Li, Yunxia Wang, Zhen Yang, Fengxia Peng. Structure and properties of silk fibroin grafted carboxylic cotton fabric via amide covalent modification. Carbohydrate Polymers, Volume 161, 2017, p. 99-108, doi. /10.1016/j.carbpol. 14. Saydalieva N.Z., Khudayberdieva D.B., F. Isamukhamedova, I. Shin. Integrated researches of the physical and mechanical properties of cotton fabric during its final finishing. E3S Web of Conferences 304, 03024 (2021) doi: 10.1051/ 03024. 15. Xu Yunhui, Huang Chen, Wang Xiaoming. Characterization and controlled release aloe extract of collagen protein modified cotton fiber. J: Carbohydr. Polym. 2013. 92, № 2, p. 982-988. 16. Hai Yan Zhang Study on Preparation of Modified Cotton with Collagen. J: Applied Mechanics and Materials. September. 2014. p: 480 – 483. |