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MAQOLA ANNOTATSIYASI

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The work is devoted to the study of photoelectric characteristics of Au-ZnxCd1-xS-Mostructured film injection photodetector sensitive in the ultraviolet and visible range of the electromagnetic radiation spectrum, with maximum sensitivity in the ultraviolet region. Analysis of spectral sensitivity indicates that in the created photodetector the photoactive layer is graded-gap, the band gap of which decreases from Eg = 3.05±0.05 eV to Eg = 2.45±0.05 eV. The study of light volt-ampere characteristics with monochromatic radiation showed that they are characterized by different values of the diode ideality factor (n) and reverse saturation current (J0). The synthesized ZnxCd1-xS layer can be used as a buffer layer in solar thin-film cells such as CdTe, CIGS and others, instead of the CdS layer, which will make it possible to increase both the shortcircuit current value and the open-circuit voltage of solar thin-film cells.

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# photodetector# short-circuit current# spectral sensitivity# solar cells# open-circuit voltage# Polycrystalline films# ZnxCd1-xS# photoelectric characteristics

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1. Н.Н. Берченко и др. Полупроводниковые твердые растворы и их применение: Справочные таблицы. М.: Воениздат, 1982. 208 с.

2. Witsey.wp.txstate.edu/files/2018/Bandgapworkfn-Heavens-3.8.pdf.

3. Y.Y. Zhan, Z.B. Shao, T.H. Jiang, J. Ye, X.F. Wu, B.C. Zhang, K. Ding, D. Wu, J.S. Jie, Cation exchange synthesis of two dimensional vertical Cu2S/CdS heterojunctions for photovoltaic device applications. J. Mater. Chem. A 8, 789 (2020). https://doi.org/10.1039/C9TA11304E

4. A.Bosio, G.Rosa, N. Romeo. Past, present and future of the thin film CdTe/CdS solar cells. Solar Energy, v.175, November 2018, Pages 31-43. https://doi.org/10.1016/j.solener2018.01.018

5. V.Bermudes. On overview on electrodeposited Cu(In,Ga)(Se,S)2 thin films for photovoltaic devices. Solar Energy, v.175, 15 November 2018, Pages 2-8. https://doi.org/10.1016/j.solener2018.03.002

6. Takuya Kato , Jyh-Lih Wu , Yoshiaki Hirai, Hiroki Sugimoto, and Veronica Bermudez. Record Efficiency for Thin-Film Polycrystalline Solar Cells Up to 22.9% Achieved by Cs-Treated Cu(In,Ga)(Se,S)2. IEEE journal of photovoltaics. 2156-3381 © 2018 IEEE. http://ieeexplore.ieee.org. DOI: 10.1109/JPHOTOV.2018.2882206.

7. Shih-Yuan Wei, Yueh-Chun Liao, Chia-Hao Hsu, Chung-Hao Cai, Wei-Chih Huang, Mao-Cheng Huang, Chih-Huang Lai. Achieving high efficiency Cu2ZnSn(S,Se)4 solar cells by non-toxic aqueous ink: Defect analysis and electrical modeling. Nano Energy, Volume 26, August 2016, Pages 74-82. https://doi.org/10.1016/j.nonoen.2016.043.059

8. M.S. De Urquijo-Ventura, M.G.S. Rao, S. Meraz-Davila, J.A.Torres-Ochoa, M.A. Quevedo-Lopez, R. Ramirez-Bon. PVPS iO2 and PVP-TiO2 hybrid films for dielectric gate applications in CdS-based thin film transistors. Polymer. V. 191, 122261 (2020) https://doi.org/10.1016/j.polymer.2020.122261

9. J. Meza-Arroyo, K. Chandra Sekhar Reddy, M.G. Syamala Rao, F. Garibay-Martínez, M.S. de UrquijoVentura1 and R. Ramírez-Bon. Solution-based CdS thin film transistors with low temperature-processed Al2O3-GPTMS-PMMA as hybrid dielectric gate. 2021 IOP Publishing Ltd. Semiconductor Science and Technology, Volume 36, Number 4. 36 045015. DOI 10.1088/1361-6641/abe01c.

10. Y.B. Zhang, F.J. Zhang, H.Z. Wang, L. Wang, F.F. Wang, Q.L. Lin, H.B. Shen, L.S. Li, High-efficiency CdSe/CdS nanorod-based red light-emitting diodes. Optics Express 27, 7935 (2019). DOI:10.1364/OE.27.007935

11. Tianwei Duan, Jing Ai, Sujie Chen, Gufeng He, Xiaojun Guo, Lu Han, Shunai Che and Yingying Duan. Chiral CdSe/CdS quantum dot (in rod)-light-emitting diodes with circularly polarized electroluminescence. Nano Rasearch, 2022, 15(10):95-37-9577. https://doi.org/10.1007/s12274-022-4536-7

12. G.Z. Wang, L.X. Gong, Z.F. Li, B. Wang, W.L. Zhang, B.F. Yuan, T.W. Zhou, X.J. Long, A.L. Kuang, A two-dimensional CdO/CdS heterostructure used for visible light photocatalysis. April 2020. Physical Chemistry Chemical Physics 22(17). DOI:10.1039/D0CP00876A

13. J.M. Hwang, M.O. Oh, I. Kim, J.K. Lee, C.S. Ha, Preparation and characterization of ZnS based nanocrystalline particles for polymer light-emitting diodes. Current Applied Physics. V.5, issue 1, January 2005, pages 31-34. https://doi.org/10.1016/.j.cap.2003.11.075

14. X.C. Yu, Q.Q. Xing, X.P. Zhang, H.L. Jiang, F.R. Cao, Photoelectrochemical water splitting using TiO2 nanorod arrays coated with Zn-doped CdS. June 2021. Journal of Materials Science 56(18), 11059 (2021). DOI:10.1007/s10853-021-06008-8.

15. S. Joishy, DD.N. Hebbar, S.D. Kulkarni, K.G. Rao, B.V.Rajendra. Band structure controlled solid solution of spray deposited Cd1-xZnxS films: investigation on photoluminescence and photo response properties. March 2020. Physica B Condensed Matter 586 (2016):412143. DOI:10.1016/j.physb.2020.412143

16. K.M. McPeak, B. Opasanont, T. Shibata, D.K. Ko, M.A.Becker, S. Chattopadhyay, H.P. Bui, T.P. Beebe, B.A. Bunker, C.B. Murray, J.B. Baxter, Microreactor chemical bath deposition of laterally graded Cd1-xZnxS thin films: a route to high through put optimization for photovoltaic buffer layers. Chemistry of Materials, 2013, 25, 3, 297–306. https://doi.org/10.1021/cm3023506

17. S.Z. Werta, O.K. Echendu, K.O. Egbo, F.B. Dejene, Electrochemical deposition and characterization of thin-film Cd1-xZnxS for solar cell application: the effect of cathodic deposition voltage. Thin Film Solids 689, 137511 (2019). https://doi.org/10.1016/j.tsf.2019. 137511

18. M. Isik, M. Terlemezoglu, S. Isik, K. Erturk, and N. M. Gasanly. The effect of Zn concentration on the structural and optical properties of Cd1-xZnxS nanostructured thin films. J Mater Sci: Mater Electron (2021) 32:25225–25233. https://doi.org/10.1007/s10854-021-06980-6.

19. R.R. Kobulov, M.A. Makhmudov, S.Y. Gerasimenko, O.K. Ataboev. “Investigation of composition and current transport mechanism in polycrystalline thin film ultra violet Au-ZnXCd1-XS-Mo- structure with narrow spectrum of photosensitivity”, Applied Solar Energy, V. 53, no.2, pp. 123, 2017. doi:10.3103/S0003701X17020098

20. R.R. Kobulov, M.A. Makhmudov, S.Y. Gerasimenko, O.K. Ataboev. “Morphology and Current Transport in a Thin-Film Polycrystalline Au–ZnxCd1-xS–Mo Structure with Wide Photosensitivity Range in the Ultraviolet and Visible Radiation Spectral Region”. Applied Solar Energy, V. 54, no. 4, pp. 251–254, 2018. doi: 10.3103/S0003701X18040084

21. S.Z. Werta, O.K. Echendu, K.O. Egbo, F.B. Dejene, Electrochemical deposition and characterization of thin-film Cd1-xZnxS for solar cell application: the effect of cathodic deposition voltage. Thin Film Solids 689, 137511 (2019)

22. M. Zakria, A. Mahmood, A. Shah, Q. Raza, T.M. Khan, E.Ahmad, Tunability of physical properties of (Cd:Zn)S thin film by close space sublimation process (CSSP). Prog. Nat. Sci. 22, 281 (2012)

23. M. Shkir, M. Anis, S.S. Shaikh, M.S. Hamdy, S. AlFaify, Impact of Se doping on optical and third-order nonlinear optical properties of spray pyrolysis fabricated CdS thin films for optoelectronics. Appl. Phys. B 127, 121 (2020)

24. Joissy Mathew, Sebin Devasia, Sadasivan Shaji, E.I. Anila. Metal–semiconductor–metal visible photodetector based on Al-doped (Cd:Zn)S nano thin films by hydrothermal synthesis. Optik, Volume 241, September 2021, 166878 https://doi.org/10.1016/j.ijleo.2021.166878

25. Sh.A. Mirsagatov, A.K. Uteniyazov, A.S. Achilov. Physics of the Solid State, 54, (2012). https://doi.org/10.1134/S1063783412090193

26. Георгобиани А. Н. Физика соединений А IIB VI . Учебное Пособие. Под редю Шейнкман М. К. М: Наука, 1986, с. 289.

1. Н.Н. Берченко и др. Полупроводниковые твердые растворы и их применение: Справочные таблицы. М.: Воениздат, 1982. 208 с.

2. Witsey.wp.txstate.edu/files/2018/Bandgapworkfn-Heavens-3.8.pdf.

3. Y.Y. Zhan, Z.B. Shao, T.H. Jiang, J. Ye, X.F. Wu, B.C. Zhang, K. Ding, D. Wu, J.S. Jie, Cation exchange synthesis of two dimensional vertical Cu2S/CdS heterojunctions for photovoltaic device applications. J. Mater. Chem. A 8, 789 (2020). https://doi.org/10.1039/C9TA11304E

4. A.Bosio, G.Rosa, N. Romeo. Past, present and future of the thin film CdTe/CdS solar cells. Solar Energy, v.175, November 2018, Pages 31-43. https://doi.org/10.1016/j.solener2018.01.018

5. V.Bermudes. On overview on electrodeposited Cu(In,Ga)(Se,S)2 thin films for photovoltaic devices. Solar Energy, v.175, 15 November 2018, Pages 2-8. https://doi.org/10.1016/j.solener2018.03.002

6. Takuya Kato , Jyh-Lih Wu , Yoshiaki Hirai, Hiroki Sugimoto, and Veronica Bermudez. Record Efficiency for Thin-Film Polycrystalline Solar Cells Up to 22.9% Achieved by Cs-Treated Cu(In,Ga)(Se,S)2. IEEE journal of photovoltaics. 2156-3381 © 2018 IEEE. http://ieeexplore.ieee.org. DOI: 10.1109/JPHOTOV.2018.2882206.

7. Shih-Yuan Wei, Yueh-Chun Liao, Chia-Hao Hsu, Chung-Hao Cai, Wei-Chih Huang, Mao-Cheng Huang, Chih-Huang Lai. Achieving high efficiency Cu2ZnSn(S,Se)4 solar cells by non-toxic aqueous ink: Defect analysis and electrical modeling. Nano Energy, Volume 26, August 2016, Pages 74-82. https://doi.org/10.1016/j.nonoen.2016.043.059

8. M.S. De Urquijo-Ventura, M.G.S. Rao, S. Meraz-Davila, J.A.Torres-Ochoa, M.A. Quevedo-Lopez, R. Ramirez-Bon. PVPS iO2 and PVP-TiO2 hybrid films for dielectric gate applications in CdS-based thin film transistors. Polymer. V. 191, 122261 (2020) https://doi.org/10.1016/j.polymer.2020.122261

9. J. Meza-Arroyo, K. Chandra Sekhar Reddy, M.G. Syamala Rao, F. Garibay-Martínez, M.S. de UrquijoVentura1 and R. Ramírez-Bon. Solution-based CdS thin film transistors with low temperature-processed Al2O3-GPTMS-PMMA as hybrid dielectric gate. 2021 IOP Publishing Ltd. Semiconductor Science and Technology, Volume 36, Number 4. 36 045015. DOI 10.1088/1361-6641/abe01c.

10. Y.B. Zhang, F.J. Zhang, H.Z. Wang, L. Wang, F.F. Wang, Q.L. Lin, H.B. Shen, L.S. Li, High-efficiency CdSe/CdS nanorod-based red light-emitting diodes. Optics Express 27, 7935 (2019). DOI:10.1364/OE.27.007935

11. Tianwei Duan, Jing Ai, Sujie Chen, Gufeng He, Xiaojun Guo, Lu Han, Shunai Che and Yingying Duan. Chiral CdSe/CdS quantum dot (in rod)-light-emitting diodes with circularly polarized electroluminescence. Nano Rasearch, 2022, 15(10):95-37-9577. https://doi.org/10.1007/s12274-022-4536-7

12. G.Z. Wang, L.X. Gong, Z.F. Li, B. Wang, W.L. Zhang, B.F. Yuan, T.W. Zhou, X.J. Long, A.L. Kuang, A two-dimensional CdO/CdS heterostructure used for visible light photocatalysis. April 2020. Physical Chemistry Chemical Physics 22(17). DOI:10.1039/D0CP00876A

13. J.M. Hwang, M.O. Oh, I. Kim, J.K. Lee, C.S. Ha, Preparation and characterization of ZnS based nanocrystalline particles for polymer light-emitting diodes. Current Applied Physics. V.5, issue 1, January 2005, pages 31-34. https://doi.org/10.1016/.j.cap.2003.11.075

14. X.C. Yu, Q.Q. Xing, X.P. Zhang, H.L. Jiang, F.R. Cao, Photoelectrochemical water splitting using TiO2 nanorod arrays coated with Zn-doped CdS. June 2021. Journal of Materials Science 56(18), 11059 (2021). DOI:10.1007/s10853-021-06008-8.

15. S. Joishy, DD.N. Hebbar, S.D. Kulkarni, K.G. Rao, B.V.Rajendra. Band structure controlled solid solution of spray deposited Cd1-xZnxS films: investigation on photoluminescence and photo response properties. March 2020. Physica B Condensed Matter 586 (2016):412143. DOI:10.1016/j.physb.2020.412143

16. K.M. McPeak, B. Opasanont, T. Shibata, D.K. Ko, M.A.Becker, S. Chattopadhyay, H.P. Bui, T.P. Beebe, B.A. Bunker, C.B. Murray, J.B. Baxter, Microreactor chemical bath deposition of laterally graded Cd1-xZnxS thin films: a route to high through put optimization for photovoltaic buffer layers. Chemistry of Materials, 2013, 25, 3, 297–306. https://doi.org/10.1021/cm3023506

17. S.Z. Werta, O.K. Echendu, K.O. Egbo, F.B. Dejene, Electrochemical deposition and characterization of thin-film Cd1-xZnxS for solar cell application: the effect of cathodic deposition voltage. Thin Film Solids 689, 137511 (2019). https://doi.org/10.1016/j.tsf.2019. 137511

18. M. Isik, M. Terlemezoglu, S. Isik, K. Erturk, and N. M. Gasanly. The effect of Zn concentration on the structural and optical properties of Cd1-xZnxS nanostructured thin films. J Mater Sci: Mater Electron (2021) 32:25225–25233. https://doi.org/10.1007/s10854-021-06980-6.

19. R.R. Kobulov, M.A. Makhmudov, S.Y. Gerasimenko, O.K. Ataboev. “Investigation of composition and current transport mechanism in polycrystalline thin film ultra violet Au-ZnXCd1-XS-Mo- structure with narrow spectrum of photosensitivity”, Applied Solar Energy, V. 53, no.2, pp. 123, 2017. doi:10.3103/S0003701X17020098

20. R.R. Kobulov, M.A. Makhmudov, S.Y. Gerasimenko, O.K. Ataboev. “Morphology and Current Transport in a Thin-Film Polycrystalline Au–ZnxCd1-xS–Mo Structure with Wide Photosensitivity Range in the Ultraviolet and Visible Radiation Spectral Region”. Applied Solar Energy, V. 54, no. 4, pp. 251–254, 2018. doi: 10.3103/S0003701X18040084

21. S.Z. Werta, O.K. Echendu, K.O. Egbo, F.B. Dejene, Electrochemical deposition and characterization of thin-film Cd1-xZnxS for solar cell application: the effect of cathodic deposition voltage. Thin Film Solids 689, 137511 (2019)

22. M. Zakria, A. Mahmood, A. Shah, Q. Raza, T.M. Khan, E.Ahmad, Tunability of physical properties of (Cd:Zn)S thin film by close space sublimation process (CSSP). Prog. Nat. Sci. 22, 281 (2012)

23. M. Shkir, M. Anis, S.S. Shaikh, M.S. Hamdy, S. AlFaify, Impact of Se doping on optical and third-order nonlinear optical properties of spray pyrolysis fabricated CdS thin films for optoelectronics. Appl. Phys. B 127, 121 (2020)

24. Joissy Mathew, Sebin Devasia, Sadasivan Shaji, E.I. Anila. Metal–semiconductor–metal visible photodetector based on Al-doped (Cd:Zn)S nano thin films by hydrothermal synthesis. Optik, Volume 241, September 2021, 166878 https://doi.org/10.1016/j.ijleo.2021.166878

25. Sh.A. Mirsagatov, A.K. Uteniyazov, A.S. Achilov. Physics of the Solid State, 54, (2012). https://doi.org/10.1134/S1063783412090193

26. Георгобиани А. Н. Физика соединений А IIB VI . Учебное Пособие. Под редю Шейнкман М. К. М: Наука, 1986, с. 289.

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