This article presents the results of a study of the polyelectrolyte nature of the
synthesized oligomers of the cationic type based on oligoisopropyloxy-monoamino -2,4,6-triamino-
1,3,5-triazolyl-ammonium chloride and their polymers, the electrical conductivity of which is
investigated, which give the result that when the solution is diluted the proportion of free
counterions increases, which contributes to an increase in the equivalent electrical conductivity of
the solution, and the viscosity of solutions of oligomeric cations on the concentration in an aqueous
solution is described by a concave curve characteristic of polyelectrolytes and their flocculating
ability has been studied, surpasses polyacrylamide in its flocculating ability, which is explained by
its multifunctionality and high molecular weight.
This article presents the results of a study of the polyelectrolyte nature of the
synthesized oligomers of the cationic type based on oligoisopropyloxy-monoamino -2,4,6-triamino-
1,3,5-triazolyl-ammonium chloride and their polymers, the electrical conductivity of which is
investigated, which give the result that when the solution is diluted the proportion of free
counterions increases, which contributes to an increase in the equivalent electrical conductivity of
the solution, and the viscosity of solutions of oligomeric cations on the concentration in an aqueous
solution is described by a concave curve characteristic of polyelectrolytes and their flocculating
ability has been studied, surpasses polyacrylamide in its flocculating ability, which is explained by
its multifunctionality and high molecular weight.
| № | Author name | position | Name of organisation |
|---|---|---|---|
| 1 | Khaydarov I.N. | teacher | TSTU |
| 2 | Ismailov I.R. | teacher | TSTU |
| 3 | Rajabova E.B. | teacher | TSTU |
| № | Name of reference |
|---|---|
| 1 | A.A. Slyusar., N.A. Shapovalov., V.A. Poluektova. “Regulation of the rheological properties of cement mixtures and concretes with additives based on oxyphenol furfural oligomers // Stroitelnye materialy”, 2008. 42. |
| 2 | A.A. Slyusar., N.A. Shapovalov., V.A. Poluektova. “Regulation of the rheological properties of cement mixtures and concretes with additives based on oxyphenol furfural oligomers // Stroitelnye materialy”, 2008. 42 |
| 3 | S.M. Mezhikovsky., A.E. Arinshtein., R.Y. Deberdeev. Oligomeric state of matter. “Science”, 2005. 252. |
| 4 | O.A. Berseneva. New generation polymers // Modern chemistry: successes and achievements: Proceedings of II Intern. Scientific conf. -Chita: “Young Scientist Publishing House”, 2016. 27. |
| 5 | M. Xie., H. Han., O. Jin., C. Du. “Synthesis of ionic hybrid polymers with polyhedral oligomeric silsesquioxane pendant by acyclic diene metathesis polymerization and characterization”, 2013. 1441. |
| 6 | W. Song., J. Wu., G. Yang., H. Han., M. Xie., X. Liao. “Precisely designed perylene bisimidesubstituted polyethylene with a high glass transition temperature and an ordered architecture”, 2015. 68765. |
| 7 | Y.S. Vygodskii., A.S. Shaplov., E.I. Lozinskaya., P.S. Vlasov., I.A. Malyshkina., N.D. Gavrilova., P.S. Kumar., M.R. Buchmeise. Cyclopolymerization of N,N-dipropargylamines and N,Ndipropargyl ammonium salts. “Macromolecules”, 2008. 1919. |
| 8 | S. Abbrent. Polymer electrolytes. “Handbook of solid state batteries”, 2016. 523 |
| 9 | O.E. Gavrilova., L.L. Nikitina. “Features of the design and manufacture of light industry products from modern complex polymer materials”, 2013. 136 |
| 10 | R.I. Ismailov. Modification of natural fibers and leathers by polymer fillers based on a polyquaternary salt. “Fibre chemistry. Springer”, 2012. 441 |
| 11 | D.R. Gagnon. Synthesis, doping, and electrical conductivity of high molecular weight poly (pphenylene vinylene). “Polymer”, 1987. 567. |
| 12 | S.K. Siddhanta., R. Gangopadhyay. Conducting polymer gel: formation of a novel semi-IPN from polyaniline and crosslinked poly (2-acrylamido-2-methyl propanesulphonicacid). “Polymer”, 2005. 2993 |
| 13 | A.T. Lawal., G.G. Wallace. Vapour phase polymerisation of conducting and non-conducting polymers: “A review Talanta”, 2014. 133 |
| 14 | R. Ansari. Polypyrrole conducting electroactive polymers: synthesis and stability studies. “Journal of chemistry”, 2006. 186 |
| 15 | R.I. Ismailov. Synthesis and mechanism of the preparation of polymeric cationic surfaceactive substances. “International journal of chemical and physical sciences”, India, 2015. 93 |
| 16 | R.M. Ismailova., U.M. Eshmukhamedov., R.I. Ismailov. Creation of an oligomeric flame retardant based on 3-chloro-1,2-hydroxypropane with 2,4,6-triamino-1,3,5-triazine. “Proceedings of the 87th scientific and technical conference of faculty, researchers and graduate students”, Minsk. 2023. 346 |