368

The article discusses the development of organomineral materials for the protection 
of metal parts of technological machines and structures operating mainly under the influence of 
an  electrochemical  environment.  A  technology  has  been  developed  for  producing  modified 
organomineral  materials  for  anticorrosive  coatings  using  micro-  and  nanosized  particles  of 
layered  silicates  (mineral  fillers).  The  mechanism  of  the  formation  of  nanocomposites  using 
layered  silicates  and  organic  materials  for  anti-corrosion  coatings  formed  by  the  activationheliotechnological  method  is  investigated.  Using  thermomechanical,  physical  and  physicochemical  methods  for  studying  the  structure  and  properties  of  the  materials  obtained.  Among 
these  methods  are:  IR  spectral  analysis,  scanning  electron  microscopy,  thermogravimetry,  as 
well  as  methods  for  determining  the  electrophysical  and  mechanical  properties.  And  the 
improvement  of  the  properties  of  organomineral  protective  coatings  due  to  the  formation  of 
nanocomplex compounds in the interfacial layers of the binder-filler is proved.

  • Internet havola
  • DOI
  • UzSCI tizimida yaratilgan sana 30-01-2020
  • O'qishlar soni 342
  • Nashr sanasi 12-12-2019
  • Asosiy tilIngliz
  • Sahifalar257-263
Ўзбек

Maolada  tehnologik  mashinalar  ishchi  sirtlarini  karroziyadan  saqlash  uchun  mahalliy 
organomineral  moddalardan  aktivacion  geliotehnologik  usulda  shakillantirilgan  antikorrozion 
qoplamalarni  olish  ,  fizik-mehanik,  tehnologik  va  ekspluaptacion  hususiyatlarini  tadqiqiy 
natijalari  keltirilgan.  qatlamli  strukturaga  ega  bo'lgan  mahalliy  mineral  va  epoksid  oligomeri 
asosida  organomineral  materiallardan  aktivacion  geliotehnologik  usulda  qoplama 
shakllantirilishida  nanokompozit  hosil  bo'lishi  mehanizimi  haqida  fikr  yuritilgan.  Olingan 
materiallarning  tuzilishi  va  hususiyatlarini  o'rganish  uchun  termomekanik,  fizik  va  fizikkimyoviy  usullardan  foydalanilgan.  Ushbu  usullar  qatoriga  quyidagilar  kiradi:  IK-spektral 
taxlil,  skanerlash  elektron  mikroskopi,  termogravimetriya,  shuningdek,  elektrofizik  va  mehanik 
hususiyatlarni  aniqlash  usullari  va  bog’lovchi  qatlamlarda  nanokompleks  aralashmalari  xosil 
bo'lishi  tufayli  organomineral  ximoya  qoplamalarining  hususiyatlari  yahshilanganligi 
isbotlangan.

Kalit so'z
English

The article discusses the development of organomineral materials for the protection 
of metal parts of technological machines and structures operating mainly under the influence of 
an  electrochemical  environment.  A  technology  has  been  developed  for  producing  modified 
organomineral  materials  for  anticorrosive  coatings  using  micro-  and  nanosized  particles  of 
layered  silicates  (mineral  fillers).  The  mechanism  of  the  formation  of  nanocomposites  using 
layered  silicates  and  organic  materials  for  anti-corrosion  coatings  formed  by  the  activationheliotechnological  method  is  investigated.  Using  thermomechanical,  physical  and  physicochemical  methods  for  studying  the  structure  and  properties  of  the  materials  obtained.  Among 
these  methods  are:  IR  spectral  analysis,  scanning  electron  microscopy,  thermogravimetry,  as 
well  as  methods  for  determining  the  electrophysical  and  mechanical  properties.  And  the 
improvement  of  the  properties  of  organomineral  protective  coatings  due  to  the  formation  of 
nanocomplex compounds in the interfacial layers of the binder-filler is proved.

Русский

В  статье  рассматривается  разработка  органоминеральных  материалов  для 
защиты  металлических  деталей  технологических  машин  и  конструкции  работающих 
преимущественно под воздействием электрохимической среды. Разработана технология 
получения  модифицированных  органоминеральных  материалов  для  антикоррозионных 
покрытий  с  применением  микро-  и  наноразмерных  частиц  слоистых  силикатов 
(минеральных  наполнителей).  Исследован  механизм  образования  нанокомпозитов  с 
применением слоистых силикатов    и органических    материалов    для    антикоррозионных 
покрытий,  сформированных  активационно-гелиотехнологически  способом. Использованы 
Mechanical  Engineering
258
термомеханические, физические и физико-химические методы исследования структуры и 
свойств  полученных  материалов.  В  числе  таких  методов:  ИК  спектральный  анализ, 
сканирующая  электронная  микроскопия,  термогравиметрия,  а  также  методы 
определения  электрофизических  и  механических  свойств.и  доказано  улучшение  свойств 
органоминеральных  защитных  покрытий  за  счет  образования  нанокомплексных 
соединений в межфазных слоях связующего наполнителя.

Kalit so'z
Muallifning F.I.Sh. Lavozimi Tashkilot nomi
1 Turabdzhanov S.M. professor TDTU
2 Lee M.S. dokorant TDTU
3 Ziyamukhamedova U.A. professor TDTU
4 Miradullaeva G.B. doktorant TDTU
Havola nomi
1 Gulyakova A, FriibingP., and Yu, Gorokhovatskiy. Relaxation processes in high-imp d polystyrene films with titanium dioxide inclusions // materialiXPMejdunar. konfZ- 26 maya).Sankt-Peterburg, 2011. T.2. S.56-5 2. ZiyamuxamedovaU.A., Shaymardanov B.A. Mexano–ximicheskiy metod modifikatsii pri razrabotke novix kompozitsionnix materialov na osnove epoksidnogo svyazuyushego i prirodnix mineralov.// Bashkirskiy ximicheskiy jurnal, 2012. T. 19. №2. S.53–57. 3. Negmatov N.S. Razrabotka effektivnoy texnologii visokokachestvennogo vollastonitovogo napolnitelya i sozdanie kompozitsionnix materialov polifunksionalnogo naznacheniya.: Avtoref. dis. kand. texn. nauk. –Tashkent, 2000. –23 s. 4. Xia, Z. Influence of porosity on stability of charge storage and piezoelectricity for porous PTFE film electrets / Z. Xia, S. Ma, X. Qiu et al. // Proceedings of 11th International Symposium on Electrets. Melbourne. Australia, 2002. – P. 326-329 5. NuriddinovB., Mamatov S., Yusupov R. Quyosh energiyasidan foydalanishning samarali yo‘llari//Vnedrenie peredovoy texnologii dlya resheniya problem toplivno– energeticheskix kompleksov: V sb. materialov Respublikanskoy nauchno–prakticheskoy konferensii. –Karshi, 2006. S. 221–223. 6. Rychkov D., Gerhard R. Stabilization of positive charge on polytetrat luoroethylene films treated with titanium-tetrachloride vapor// Appl. Phys. Lett.,2011, Vol. 98, p. (122901) 7. ZiyamuxamedovaU.A., RaximovG.N.. Fiziko–ximicheskie i mexanicheskie osnovi sozdaniya nanokompleksnix soedineniy v geterokompozitax// Poluchenie nanokompozitov, ix struktura i svoystva: Materiali Respublikanskoy nauchno– texnicheskoy konferensii s uchastiem zarubejnix uchyonix. – Tashkent, 2007. –226 s. 8. Negmatov Saibjan, Ziyamukhamedova Umida, Rakhimov Ganisher. Modified Epoxide Binding for Antifric–tional Coverings at Interaction with the Cotton.// European Polymer Congress 2005. –Moscow, Russia. P1.2–66, Ref 4869. 9. Rychkov D., Yablokov M„ Rychkov A. Chemical and physical surface modification of PTFE films-an approach to produce stable electrets.// Applied Physics A: Materials Science & Processing, 2012,Vol. 107, Number 3, pp. 589-596. 10. Ziyamuxamedova U.A., Kuluev A.R., Raximov G.N., Ubaydullaev S.K., Negmatova M.I., Djumabaev A.B. Issledovanie vozmojnosti ispolzovaniya geliotexnologii pri sozdanii mashinostroitelnix materialov i pokritiy iz nix. / Tr. Mejdunar. konf. «Vozobnovlyaemie istochniki energii i geliomaterialovedenie». – Tashkent, 2005. S. 185–186. 11. Xabibullaev A.X., ZiyamuxamedovaU.A. Geliotexnologiya usulida polimer bog‘lovchilar asosidagi geterokompozitlarning xususiyatlarini yaxshilash imkoniyatlarini tadqiqotlash// ToshDTU Xabarlari. – Toshkent, 2010. – №3. S.132–134. 12. Negmatov Soibjon, Ziyamukhamedova Umida, Rahimov Ganijon, Negmatova Malika, Djumabaev Alijon. Physico–Chemistry of Friction Interaction of Synthesis and Natural Polymer Materials// XIX Ulusal Kimya Kongresi, Kuşadasi, Tűrkiye. 2005. FKP. – 69 r. 13. Rychkov D., Gerhard R, Ivanov V., RychkovA. Enhanced Electret Charge Stability on Polyethylene Films Treated with Titanium-Tetrachloride Vapor.// IEEE Transactions on Dielectrics and Electrical Insulation, 2012,Vol. 19, Issue 4, pp. 1305-1311. 14. Ziamukhamedova U.A., Shaymardanov B.A. Research of the possibility of hardening the hydro–abrasive endurance of anticorrosive epoxy hetero-composite coats with usage Mechanical Engineering 263 of local raw materials//VsbMejdun. konf. Ximicheskaya texnologiya 2012. Moskva 27marta 2012. S. 300–302 15. Ziyamuxamedova U.A., Raximov G.N., DjumabaevD.A. Aktivatsionno– geliotexnologicheskiy metod sozdaniya nanokompleksnix soedineniy //INNOVATION– 2007: Sb. nauchnix statey Mejdunarodnoy konferensii. – Tashkent, 2007. S.184–186. 16. Ziyamuxamedova U.A. Perspektivnie kompozitsionnie materiali na osnove mestnix sirevix i energeticheskix resursov. –Tashkent: TashGTU, 2011. –160 s. 17. Ziamukhamedova U.A., Shaymardanov B.A. Research of the possibility of hardening the hydro–abrasive endurance of anticorrosive epoxy hetero-composite coats with usage of local raw materials//VsbMejdun. konf. Ximicheskaya texnologiya 2012. Moskva 27marta 2012. S. 300–302 18. ZiyamuhamedovaU. A., DjumabaevD.. Kapsamlı bir yöntem değişiklikler geterokompozıtov epoksi, ve diğer yerel mineraller//Kirikkaleuniversitetijornali – 45–47 b. №2. 2012 19. Ziyamuxamedova U.A i dr. Antikorrozionnie i gidroabrazivno-iznosostoykie geterokompozitnie materiali na osnove polimerov i mestnix mineralov. Toshkent: «TGTU»,-2015,-192S 20 . ГОСТ Р58284-2018 Obщie trebovaniya k zaщite ot korrozii.
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